Richard S. Ruffine Hartree Self Consistent Method for the Scattering of Positrons by Hydrogen Atoms

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Whilst the greatest effort has been made to ensure the quality of this text, due to the historical nature of this content, in some rare cases there may be minor issues with legibility. Our aim has been to develop a method whereby the self - consistent features of the Hartree approach can be incorporated into a form.for the wave function which will contain correlations and satisfy the asymptotic boundary conditions. We have accomplished this by adding a sum of products of one particle functions to a product of the unperturbed bound state wave function and a function which will have the proper asymp totic form for a scattered particle. By requiring the terms in the sum to vanish at large distances, we have been able to obtain a set of coupled differential equations for the one particle functions. We can show that these differential equations lead to an effective one-particle Hamiltonian for the scattered particle in which the potential is made up of a sum of induced multipole potentials. We can also show that with a suitable set of approximations, the equations reduce to the adiabatic approximation.